聚酮类结构的迭代方法：利用催化不对称奥弗曼酯化反应立体选择性合成1,3 - 多元醇
Iterative approach to polyketide-type structures: stereoselective synthesis of 1,3-polyols utilizing the catalytic asymmetric Overman esterification.
作者信息
Binder Jörg T, Kirsch Stefan F
机构信息
Department Chemie, Technische Universität München, Lichtenbergstr. 4, 85747 Garching, Germany.
出版信息
Chem Commun (Camb). 2007 Oct 28(40):4164-6. doi: 10.1039/b708248g. Epub 2007 Aug 6.
DOI:10.1039/b708248g
PMID:17925963
Abstract
An iterative systematic approach to the 1,3-polyol motif has been developed to provide access to all possible stereoisomers by utilizing the catalytic asymmetric Overman esterification for the construction of all stereogenic centres.
摘要
已开发出一种针对1,3 - 多元醇基序的迭代系统方法，通过利用催化不对称奥弗曼酯化反应构建所有立体中心，以获得所有可能的立体异构体。
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