铱（I）催化手性支链苄基烯丙基亚氨基二羧酸酯的立体特异性脱羧烯丙基酰胺化反应。
Iridium(I)-catalyzed stereospecific decarboxylative allylic amidation of chiral branched benzyl allyl imidodicarboxylates.
作者信息
Singh Om V, Han Hyunsoo
机构信息
Department of Chemistry, The University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249, USA.
出版信息
Org Lett. 2007 Nov 8;9(23):4801-4. doi: 10.1021/ol702115h. Epub 2007 Oct 13.
PMID:17935343
Abstract
Ir(I)-catalyzed decarboxylative allylic amidation of chiral branched benzyl allyl imidodicarboxylates has been shown to proceed with complete retention of enantiomeric purity and configuration. The transformation is stereospecific and appears to be quite general, accommodating a wide range of R groups.
摘要
铱（I）催化的手性支链苄基烯丙基亚氨基二羧酸酯的脱羧烯丙基酰胺化反应已被证明在对映体纯度和构型完全保持的情况下进行。该转化具有立体专一性，并且似乎相当普遍，能容纳多种R基团。
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