Chiral molecular ferromagnets based on copper(II) polymers with end-on azido bridges.
作者信息
Gu Zhi-Guo, Song You, Zuo Jing-Lin, You Xiao-Zeng
机构信息
Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People's Republic of China.
出版信息
Inorg Chem. 2007 Nov 12;46(23):9522-4. doi: 10.1021/ic7015325. Epub 2007 Oct 16.
PMID:17939656
Abstract
Two homochiral two-dimensional brick-wall complexes with only end-on azido bridges, [Cu3((R)-phea)2(N3)6]n (1) and [Cu3((S)-phea)2(N3)6]n (2) (phea=1-phenylethylamine), have been synthesized and structurally characterized. Magnetic studies show that both complexes are chiral ferromagnets with the magnetic transition temperature at 5.5 K.
摘要
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