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Poly[di-μ(2)-azido-μ(3)-pyrazine-2-carboxyl-ato-cadmium(II)].

作者信息

Li Cai-Yun, Li Pei-Fan, Jin Hui-Min

机构信息

Department of Pharmaceutical Science, Tianjin Medical College, Tianjin 300222, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 10;65(Pt 5):m502. doi: 10.1107/S1600536809012227.

Abstract

The title compound, Cd(C(5)H(3)N(2)O(2))(N(3)), has been pre-pared by the reaction of pyrazine-2-carboxylic acid, cadmium(II) nitrate and sodium azide. In the structure, the Cd(II) atom is six-coordinated by two azide anions and three pyrazine-2-carboxyl-ate ligands. Each pyrazine-2-carboxyl-ate ligand bridges three Cd(II) atoms, whereas the azide ligand bridges two Cd(II) atoms, resulting in the formation of a two-dimensional metal-organic polymer developing parallel to the (100) plane.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed97/2977564/6261f52a46a3/e-65-0m502-fig1.jpg

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