铜（I）介导的官能化炔基锂与芳基镁试剂之间的氧化交叉偶联反应。 - Suppr

Copper(I)-mediated oxidative cross-coupling between functionalized alkynyl lithium and aryl magnesium reagents.

作者信息

Dubbaka Srinivas Reddy, Kienle Marcel, Mayr Herbert, Knochel Paul

机构信息

Ludwig-Maximilians-Universität München, Department Chemie und Biochemie, Butenandtstrasse 5-13, Haus F, 81377 München, Germany.

出版信息

Angew Chem Int Ed Engl. 2007;46(47):9093-6. doi: 10.1002/anie.200703097.

DOI:10.1002/anie.200703097

PMID:17943941

Abstract

摘要

相似文献

Copper(I)-mediated oxidative cross-coupling between functionalized alkynyl lithium and aryl magnesium reagents.

Angew Chem Int Ed Engl. 2007;46(47):9093-6. doi: 10.1002/anie.200703097.

Iron-catalyzed aryl-aryl cross-couplings with magnesium-derived copper reagents.

Angew Chem Int Ed Engl. 2005 Mar 4;44(11):1654-8. doi: 10.1002/anie.200462013.

A straightforward alkynylation of Li and Mg metalated heterocycles with sulfonylacetylenes.

Chem Commun (Camb). 2015;51(2):346-9. doi: 10.1039/c4cc07574a. Epub 2014 Nov 14.

C(aryl)-C(alkyl) bond formation from Cu(ClO4)2-mediated oxidative cross coupling reaction between arenes and alkyllithium reagents through structurally well-defined Ar-Cu(III) intermediates.

Chem Commun (Camb). 2012 Sep 28;48(75):9418-20. doi: 10.1039/c2cc35067j. Epub 2012 Aug 14.

Highly regioselective preparation of heteroaryl-magnesium reagents by using a Br/Mg exchange.

Chemistry. 2012 Dec 7;18(50):16145-52. doi: 10.1002/chem.201202230. Epub 2012 Oct 15.

Metalated nitriles: organolithium, -magnesium, and -copper exchange of alpha-halonitriles.

J Org Chem. 2005 Mar 18;70(6):2200-5. doi: 10.1021/jo047877r.

Preparation of heterocyclic amines by an oxidative amination of zinc organometallics mediated by Cu(I): a new oxidative cycloamination for the preparation of annulated indole derivatives.

Chem Asian J. 2011 Feb 1;6(2):517-23. doi: 10.1002/asia.201000367.

Heteroaromatic thioether-organostannane cross-coupling.

Org Lett. 2003 Mar 20;5(6):801-2. doi: 10.1021/ol0273497.

Convenient electrophilic fluorination of functionalized aryl and heteroaryl magnesium reagents.

Angew Chem Int Ed Engl. 2010 Mar 15;49(12):2215-8. doi: 10.1002/anie.200905052.

Improved synthesis of aryltrialkoxysilanes via treatment of aryl Grignard or lithium reagents with tetraalkyl orthosilicates.

J Org Chem. 2004 Nov 26;69(24):8305-14. doi: 10.1021/jo048667h.

引用本文的文献

Ring forming transformations of ynamides cycloaddition.

RSC Adv. 2023 Apr 4;13(16):10715-10756. doi: 10.1039/d3ra00139c. eCollection 2023 Apr 3.

Computational exploration for possible reaction pathways, regioselectivity, and influence of substrate in gold-catalyzed cycloaddition of cyanamides with enynamides.

RSC Adv. 2022 Aug 15;12(35):22939-22945. doi: 10.1039/d2ra02682a. eCollection 2022 Aug 10.

Directed regioselective ,'-magnesiations of aromatics and heterocycles using BuMg in toluene.

Chem Sci. 2021 May 18;12(24):8424-8429. doi: 10.1039/d1sc01777b.

Copper-Catalyzed Oxidative Cross-Coupling of Electron-Deficient Polyfluorophenylboronate Esters with Terminal Alkynes.

Chemistry. 2020 Dec 18;26(71):17267-17274. doi: 10.1002/chem.202002888. Epub 2020 Nov 9.

Nickel, manganese, cobalt, and iron-catalyzed deprotonative arene dimerization.

Org Lett. 2010 Mar 19;12(6):1200-3. doi: 10.1021/ol902970z.

An aromatic Glaser-Hay reaction.

J Am Chem Soc. 2009 Dec 2;131(47):17052-3. doi: 10.1021/ja907479j.

文献AI研究员

20分钟写一篇综述，助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型，支持多种主流文档格式。

立即体验

Copper(I)-mediated oxidative cross-coupling between functionalized alkynyl lithium and aryl magnesium reagents.

作者信息

Dubbaka Srinivas Reddy, Kienle Marcel, Mayr Herbert, Knochel Paul

机构信息

Ludwig-Maximilians-Universität München, Department Chemie und Biochemie, Butenandtstrasse 5-13, Haus F, 81377 München, Germany.

出版信息

Angew Chem Int Ed Engl. 2007;46(47):9093-6. doi: 10.1002/anie.200703097.

DOI:10.1002/anie.200703097

PMID:17943941

Abstract

摘要

相似文献

Copper(I)-mediated oxidative cross-coupling between functionalized alkynyl lithium and aryl magnesium reagents.

Angew Chem Int Ed Engl. 2007;46(47):9093-6. doi: 10.1002/anie.200703097.

Iron-catalyzed aryl-aryl cross-couplings with magnesium-derived copper reagents.

Angew Chem Int Ed Engl. 2005 Mar 4;44(11):1654-8. doi: 10.1002/anie.200462013.

A straightforward alkynylation of Li and Mg metalated heterocycles with sulfonylacetylenes.

Chem Commun (Camb). 2015;51(2):346-9. doi: 10.1039/c4cc07574a. Epub 2014 Nov 14.

C(aryl)-C(alkyl) bond formation from Cu(ClO4)2-mediated oxidative cross coupling reaction between arenes and alkyllithium reagents through structurally well-defined Ar-Cu(III) intermediates.

Chem Commun (Camb). 2012 Sep 28;48(75):9418-20. doi: 10.1039/c2cc35067j. Epub 2012 Aug 14.

Highly regioselective preparation of heteroaryl-magnesium reagents by using a Br/Mg exchange.

Chemistry. 2012 Dec 7;18(50):16145-52. doi: 10.1002/chem.201202230. Epub 2012 Oct 15.

Metalated nitriles: organolithium, -magnesium, and -copper exchange of alpha-halonitriles.

J Org Chem. 2005 Mar 18;70(6):2200-5. doi: 10.1021/jo047877r.

Preparation of heterocyclic amines by an oxidative amination of zinc organometallics mediated by Cu(I): a new oxidative cycloamination for the preparation of annulated indole derivatives.

Chem Asian J. 2011 Feb 1;6(2):517-23. doi: 10.1002/asia.201000367.

Heteroaromatic thioether-organostannane cross-coupling.

Org Lett. 2003 Mar 20;5(6):801-2. doi: 10.1021/ol0273497.

Convenient electrophilic fluorination of functionalized aryl and heteroaryl magnesium reagents.

Angew Chem Int Ed Engl. 2010 Mar 15;49(12):2215-8. doi: 10.1002/anie.200905052.

Improved synthesis of aryltrialkoxysilanes via treatment of aryl Grignard or lithium reagents with tetraalkyl orthosilicates.

J Org Chem. 2004 Nov 26;69(24):8305-14. doi: 10.1021/jo048667h.

引用本文的文献

Ring forming transformations of ynamides cycloaddition.

RSC Adv. 2023 Apr 4;13(16):10715-10756. doi: 10.1039/d3ra00139c. eCollection 2023 Apr 3.

Computational exploration for possible reaction pathways, regioselectivity, and influence of substrate in gold-catalyzed cycloaddition of cyanamides with enynamides.

RSC Adv. 2022 Aug 15;12(35):22939-22945. doi: 10.1039/d2ra02682a. eCollection 2022 Aug 10.

Directed regioselective ,'-magnesiations of aromatics and heterocycles using BuMg in toluene.

Chem Sci. 2021 May 18;12(24):8424-8429. doi: 10.1039/d1sc01777b.

Copper-Catalyzed Oxidative Cross-Coupling of Electron-Deficient Polyfluorophenylboronate Esters with Terminal Alkynes.

Chemistry. 2020 Dec 18;26(71):17267-17274. doi: 10.1002/chem.202002888. Epub 2020 Nov 9.

Nickel, manganese, cobalt, and iron-catalyzed deprotonative arene dimerization.

Org Lett. 2010 Mar 19;12(6):1200-3. doi: 10.1021/ol902970z.

An aromatic Glaser-Hay reaction.

J Am Chem Soc. 2009 Dec 2;131(47):17052-3. doi: 10.1021/ja907479j.

Copper(I)-mediated oxidative cross-coupling between functionalized alkynyl lithium and aryl magnesium reagents.

作者信息

机构信息

出版信息

相似文献

引用本文的文献

文献AI研究员

用中文搜PubMed

文档翻译

Suppr 超能文献

Copper(I)-mediated oxidative cross-coupling between functionalized alkynyl lithium and aryl magnesium reagents.

作者信息

机构信息

出版信息

相似文献

引用本文的文献