在TpRh(C2H4)2/PPh3体系催化下，伯胺和仲胺对末端炔烃的反马氏加成反应。 - Suppr

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超能文献

Anti-Markovnikov addition of both primary and secondary amines to terminal alkynes catalyzed by the TpRh(C2H4)2/PPh3 system.

作者信息

Fukumoto Yoshiya, Asai Harumi, Shimizu Masaki, Chatani Naoto

机构信息

Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.

出版信息

J Am Chem Soc. 2007 Nov 14;129(45):13792-3. doi: 10.1021/ja075484e. Epub 2007 Oct 20.

DOI:10.1021/ja075484e

PMID:17949090

Abstract

摘要

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Anti-Markovnikov addition of both primary and secondary amines to terminal alkynes catalyzed by the TpRh(C2H4)2/PPh3 system.

作者信息

Fukumoto Yoshiya, Asai Harumi, Shimizu Masaki, Chatani Naoto

机构信息

Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.

出版信息

J Am Chem Soc. 2007 Nov 14;129(45):13792-3. doi: 10.1021/ja075484e. Epub 2007 Oct 20.

DOI:10.1021/ja075484e

PMID:17949090

Abstract

摘要

相似文献

Anti-Markovnikov addition of both primary and secondary amines to terminal alkynes catalyzed by the TpRh(C2H4)2/PPh3 system.

J Am Chem Soc. 2007 Nov 14;129(45):13792-3. doi: 10.1021/ja075484e. Epub 2007 Oct 20.

Rhodium-catalyzed asymmetric addition of terminal alkynes to diarylphosphinylallenes.

Chem Asian J. 2008 Sep 1;3(8-9):1505-10. doi: 10.1002/asia.200800042.

Cobalt-catalyzed intermolecular C-H amination with bromamine-T as nitrene source.

Chem Commun (Camb). 2007 Nov 28(44):4644-6. doi: 10.1039/b710677g. Epub 2007 Sep 3.

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Angew Chem Int Ed Engl. 2004 Nov 19;43(45):6125-8. doi: 10.1002/anie.200461338.

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Chem Commun (Camb). 2009 Sep 14(34):5141-3. doi: 10.1039/b910198e. Epub 2009 Jul 28.

Rhodium(III)-catalyzed cyclization-olefination of N-acetoxyl ketoimine-alkynes.

Org Lett. 2012 Jul 6;14(13):3400-3. doi: 10.1021/ol301371p. Epub 2012 Jun 12.

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J Am Chem Soc. 2003 May 14;125(19):5608-9. doi: 10.1021/ja0293608.

Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes.

Chem Commun (Camb). 2006 Sep 14(34):3646-7. doi: 10.1039/b605368h. Epub 2006 Aug 2.

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Highly regioselective hydroaminomethylation of terminal olefins to linear amines using Rh complexes with a Tetrabi phosphorus ligand.

Chemistry. 2011 Dec 16;17(51):14559-63. doi: 10.1002/chem.201103073. Epub 2011 Nov 21.

引用本文的文献

Anti-Markovnikov Intermolecular Hydroamination of Alkenes and Alkynes: A Mechanistic View.

Chem Rev. 2023 Aug 9;123(15):9139-9203. doi: 10.1021/acs.chemrev.2c00482. Epub 2023 Jul 5.

Rhodium-/Iridium-Catalyzed Hydroamination for the Synthesis of 1,2-, 1,3-, or 1,4-Diamines.

ACS Catal. 2022 Jul 15;12(14):8331-8340. doi: 10.1021/acscatal.2c01835. Epub 2022 Jun 28.

Rhodium-Catalyzed Anti-Markovnikov Transfer Hydroiodination of Terminal Alkynes.

Angew Chem Int Ed Engl. 2023 Jan 23;62(4):e202214071. doi: 10.1002/anie.202214071. Epub 2022 Dec 20.

Recent progress in the chemistry of β-aminoketones.

RSC Adv. 2022 Aug 31;12(38):24681-24712. doi: 10.1039/d2ra03864a. eCollection 2022 Aug 30.

Fullerene C promoted photochemical hydroamination reactions of an electron deficient alkyne with trimethylsilyl group containing tertiary -alkylbenzylamines.

RSC Adv. 2021 Feb 3;11(11):5914-5922. doi: 10.1039/d1ra00166c. eCollection 2021 Feb 2.

Facile Hydrogenative Deprotection of -Benzyl Groups Using a Mixed Catalyst of Palladium and Niobic Acid-on-Carbon.

ACS Omega. 2020 Feb 5;5(6):2699-2709. doi: 10.1021/acsomega.9b03226. eCollection 2020 Feb 18.

A minireview of hydroamination catalysis: alkene and alkyne substrate selective, metal complex design.

BMC Chem. 2019 Jul 11;13(1):89. doi: 10.1186/s13065-019-0606-7. eCollection 2019 Dec.

Rhodium-Catalyzed Enantioselective Hydroamination of Alkynes with Indolines.

J Am Chem Soc. 2015 Jul 8;137(26):8392-5. doi: 10.1021/jacs.5b05200. Epub 2015 Jun 29.