铑催化的通过区域选择性 C-H 键断裂的芳基亚胺与内部炔烃的氧化偶联。
Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C-H bond cleavage.
机构信息
Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.
出版信息
Chem Commun (Camb). 2009 Sep 14(34):5141-3. doi: 10.1039/b910198e. Epub 2009 Jul 28.
DOI:10.1039/b910198e
PMID:20448973
Abstract
The rhodium-catalyzed oxidative coupling of aromatic imines with alkynes effectively proceeds via regioselective C-H bond cleavage to produce indenone imine and isoquinoline derivatives.
摘要
铑催化的芳基亚胺与炔烃的氧化偶联反应可以通过区域选择性的 C-H 键断裂有效地进行，生成茚酮亚胺和异喹啉衍生物。
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