有机催化的π-烯丙基钯配合物的环化反应：一种构建五元环和六元环的新方法。
Organocatalyzed cyclizations of pi-allylpalladium complexes: a new method for the construction of five- and six-membered rings.
作者信息
Bihelovic Filip, Matovic Radomir, Vulovic Bojan, Saicic Radomir N
机构信息
Faculty of Chemistry, University of Belgrade, Studentski trg 16, P. O. Box. 158, 11000 Belgrade, Serbia.
出版信息
Org Lett. 2007 Nov 22;9(24):5063-6. doi: 10.1021/ol7023554. Epub 2007 Oct 24.
PMID:17958367
Abstract
Synergic combination of organotransition metal catalysis and organocatalysis allows, for the first time, the Tsuji-Trost cyclization of aldehydes. A catalytic asymmetric variant of the reaction is also possible.
摘要
有机过渡金属催化与有机催化的协同结合首次实现了醛的辻 - 特罗斯特环化反应。该反应的催化不对称变体也是可行的。
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