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Hydrogen fluoride-mediated synthesis of 1-thiotrehaloses involving reaction of D-glucose with hydrogen sulfide.

作者信息

Defaye J, Gadelle A, Pedersen C

机构信息

Département de Recherche Fondamentale, C.N.R.S., Centre d'Etudes Nucléaires, Grenoble, France.

出版信息

Carbohydr Res. 1991 Sep 18;217:51-8. doi: 10.1016/0008-6215(91)84116-v.

DOI:10.1016/0008-6215(91)84116-v
PMID:1797406
Abstract

Hydrogen sulfide reacted with D-glucose in hydrogen fluoride solution to yield preponderantly alpha,alpha-1-thiotrehalose, beta,beta-1-thiotrehalose, and the alpha,beta anomer. Conditions were found under which the thiotrehaloses were obtained in the respective proportions of 8:5:5.

摘要

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