Szczepura Lisa F, Oh Meghan K, Knott Stanley A
Department of Chemistry, Illinois State University, Campus Box 4160, Normal, IL 61790, USA.
Chem Commun (Camb). 2007 Nov 28(44):4617-9. doi: 10.1039/b708390d. Epub 2007 Oct 19.
The linkage isomers Re(6)Se(8)(PEt(3))(5)(1,5-MeN(4)C) and Re(6)Se(8)(PEt(3))(5)(2,5-MeN(4)C) were generated upon reaction of tetrabutylammonium azide with the corresponding acetonitrile complex, Re(6)Se(8)(PEt(3))(5)(NCCH(3)); these are the first (tetrazolato)rhenium complexes reported to date.
叠氮化四丁基铵与相应的乙腈配合物Re(6)Se(8)(PEt(3))(5)(NCCH(3))反应生成了键合异构体Re(6)Se(8)(PEt(3))(5)(1,5-MeN(4)C)和Re(6)Se(8)(PEt(3))(5)(2,5-MeN(4)C);这些是迄今为止报道的首例(四唑根)铼配合物。