色满酮的合成：一种新型钯催化的瓦克型氧化环化反应，涉及1,5-氢化物从烷基迁移至钯。

Synthesis of chromanones: a novel palladium-catalyzed Wacker-type oxidative cyclization involving 1,5-hydride alkyl to palladium migration.

作者信息

Zhang Zuhui, Pan Chongfeng, Wang Zhiyong

机构信息

Hefei National Laboratory for Physical Science at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, PR China.

出版信息

Chem Commun (Camb). 2007 Nov 28(44):4686-8. doi: 10.1039/b711613f. Epub 2007 Aug 29.

DOI:10.1039/b711613f

PMID:17989833

Abstract

A series of 2-methylchromanone derivatives have been prepared by using a novel palladium-catalyzed Wacker-type oxidative cyclization, in which a 1,5-hydride alkyl to palladium migration and a direct chirality transfer were involved.

摘要

通过一种新型钯催化的瓦克型氧化环化反应制备了一系列2-甲基色满酮衍生物，该反应涉及1,5-氢化物向钯的烷基迁移和直接的手性转移。