Oleinikova Alla, Brovchenko Ivan
Physical Chemistry, University of Dortmund, Otto-Hahn-Str. 6, Dortmund, D-44227, Germany.
Phys Rev E Stat Nonlin Soft Matter Phys. 2007 Oct;76(4 Pt 1):041603. doi: 10.1103/PhysRevE.76.041603. Epub 2007 Oct 18.
Density profiles of Lennard-Jones liquid confined in slit pore with weakly attractive or hard walls are studied along the pore coexistence curve. In the large pores, the thickness L0 of a drying layer increases approximately as the bulk correlation length xi- when approaching the bulk critical temperature Tc. Strengthening of the fluid-wall interaction suppresses the thickness of a drying layer and yields a logarithmic growth of L0 with tau=1-T/Tc. Existence of the two distinct regimes in the temperature behavior of L0 may reflect a partial drying transition expected for the weak long-range fluid-wall interactions. Confinement in small pores suppresses strongly the drying layer and its thickness grows as approximately ln(tau) upon heating with subsequent saturation. The sharpness of the interface between a liquid and a drying layer is studied in dependence on the fluid-wall interaction and pore width.