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蠕虫状胶束溶液中的交替涡旋带

Alternating vorticity bands in a solution of wormlike micelles.

作者信息

Herle Vishweshwara, Kohlbrecher Joachim, Pfister Bruno, Fischer Peter, Windhab Erich J

机构信息

Institute of Food Science and Nutrition, ETH Zurich, 8092 Zurich, Switzerland.

出版信息

Phys Rev Lett. 2007 Oct 12;99(15):158302. doi: 10.1103/PhysRevLett.99.158302. Epub 2007 Oct 10.

Abstract

We report on structural characterization of vorticity bands formed in a wormlike micellar solution by Rheo--small-angle neutron scattering and video imaging experiments. Below a critical shear stress tau{c} in Newtonian and shear-thinning regime, only a minor flow alignment of the micelles is observed. Above tau{c}, in the shear-thickening regime, alternating transparent and turbid bands are formed. Triggered small-angle neutron scattering shows different anisotropic patterns in both bands indicating strongly aligned structures. By high-speed video imaging, we show that such an alignment of micelles does not correspond to a phase of lower viscosity.

摘要

我们通过流变小角中子散射和视频成像实验,报告了在蠕虫状胶束溶液中形成的涡带的结构特征。在牛顿流体和剪切变稀区域低于临界剪切应力τc时,仅观察到胶束的轻微流动排列。在τc以上的剪切增稠区域中,形成了交替的透明带和混浊带。触发小角中子散射显示两个带中存在不同的各向异性模式,表明结构高度排列。通过高速视频成像,我们表明这种胶束排列并不对应于较低粘度的相。

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