Ince M, Yildiz F, Engin G Onkal, Engin S N, Keskinler B
Gebze Institute of Technology, Department of Environmental Engineering, Gebze 41400, Kocaeli, Turkey.
J Hazard Mater. 2008 May 30;153(3):991-8. doi: 10.1016/j.jhazmat.2007.09.069. Epub 2007 Sep 25.
A novel circulating jet loop bioreactor adapted for organic matter oxidation has been designed and constructed. In this study, the input was leachate samples collected from Kemerburgaz Odayeri waste landfill site located on the European side of Istanbul. Controlling the jet loop bioreactor to realize high rates of purification depends on maintaining the appropriate loadings and operating conditions. This requires collecting various system data to estimate the dynamics of the system satisfactorily with the aim of keeping certain parameters within the specified range. The differential transform method (DTM) based solution of the state equations reveals the current state of the process so that any deviation in the system parameters can be immediately detected and regulated accordingly. The respirometric method for kinetic parameter calculations for biodegradation has been used for some time. In many studies, the respirometer was designed separately, usually in bench-scale. However, when a separate respirometer is used, the scale effect and parameters that affect the hydrodynamic structure of the system should be taken into consideration. In this study, therefore, the jet loop reactor itself was used as a respirometer. Thus, the kinetic parameters found reflecting the characteristics of microorganisms used for biodegradation would be more realistic. If the main reactor, here the jet loop reactor, would be used as the respirometer, the kinetic parameter changes can easily be monitored in the long run. Using the bioreactor as a respirometer, the most important kinetic parameters, Ks, kd and micromax were found to be 11,000 mg L(-1), 0.019 day(-1), and 0.21 day(-1), respectively. The stoichiometric coefficient, Y, was found to be 0.28 gr gr(-1) for the present system.
一种适用于有机物氧化的新型循环喷射环流生物反应器已被设计和构建。在本研究中,输入物是从位于伊斯坦布尔欧洲一侧的凯梅尔堡加兹奥代里垃圾填埋场采集的渗滤液样本。控制喷射环流生物反应器以实现高净化率取决于维持适当的负荷和操作条件。这需要收集各种系统数据,以便令人满意地估计系统动态,目的是将某些参数保持在指定范围内。基于微分变换法(DTM)求解状态方程可揭示过程的当前状态,从而可以立即检测到系统参数的任何偏差并相应地进行调节。用于生物降解动力学参数计算的呼吸测量法已经使用了一段时间。在许多研究中,呼吸计通常是单独设计的,通常是实验室规模。然而,当使用单独的呼吸计时,应考虑规模效应和影响系统流体动力学结构的参数。因此,在本研究中,喷射环流反应器本身被用作呼吸计。这样,所发现的反映用于生物降解的微生物特性的动力学参数将更符合实际情况。如果主反应器,即这里的喷射环流反应器,用作呼吸计,从长远来看可以很容易地监测动力学参数的变化。将生物反应器用作呼吸计,发现最重要的动力学参数Ks、kd和μm分别为11,000 mg L(-1)、0.019 day(-1)和0.21 day(-1)。对于本系统,化学计量系数Y为0.28 gr gr(-1)。