X-ray and neutron diffraction studies of water-encapsulated inside potassium aryloxide aggregates: complementary host-guest stabilization of mono- and dihydrated cages.
作者信息
Morris J Jacob, Noll Bruce C, Schultz Arthur J, Piccoli Paula M B, Henderson Kenneth W
机构信息
Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA.
出版信息
Inorg Chem. 2007 Dec 10;46(25):10473-5. doi: 10.1021/ic7018082. Epub 2007 Nov 13.
PMID:17997552
Abstract
The controlled hydrolysis of potassium 2-tert-butylphenoxide or 2-isopropylphenoxide leads to the unexpected encapsulation of the water inside K6O6 hexameric drum aggregates. Encapsulation of the neutral molecules is enabled in these instances through the formation of strong hydrogen bonds and dative interactions between the host and guest.
摘要
Zotero 插件