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New trifluoromethylated derivatives of [60]fullerene, C60(CF3)n with n = 12 and 14.

作者信息

Omelyanyuk Nadezhda A, Goryunkov Alexey A, Tamm Nadezhda B, Avdoshenko Stanislav M, Ioffe Ilya N, Sidorov Lev N, Kemnitz Erhard, Troyanov Sergey I

机构信息

Chemistry Department, Moscow State University, Leninskie Gory, 119992 Moscow, Russia.

出版信息

Chem Commun (Camb). 2007 Dec 7(45):4794-6. doi: 10.1039/b709684d. Epub 2007 Sep 5.

Abstract

New isomers of C(60)(CF(3))(12) and C(60)(CF(3))(14) have been isolated from mixtures obtained via reaction of C(60) or S(6)-C(60)(CF(3))(12) with CF(3)I; they were characterized by single crystal XRD study and investigated theoretically by means of DFT calculations.

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