C70(CF3)16和C70(CF3)18的制备、晶体学表征及理论研究
Preparation, crystallographic characterization and theoretical study of C70(CF3)16 and C70(CF3)18.
作者信息
Avdoshenko Stanislav M, Goryunkov Alexey A, Ioffe Ilya N, Ignat'eva Daria V, Sidorov Lev N, Pattison Philip, Kemnitz Erhard, Troyanov Sergey I
机构信息
Chemistry Department, Moscow State University, Leninskie Gory, 119992 Moscow, Russia.
出版信息
Chem Commun (Camb). 2006 Jun 21(23):2463-5. doi: 10.1039/b603201j. Epub 2006 May 3.
DOI:10.1039/b603201j
PMID:16758016
Abstract
C70(CF3)16 and C70(CF3)18, the first trifluoromethylated fullerene derivatives to comprise a pair of adjacent CF3 groups, have been isolated from a mixture obtained via reaction of C70 with CF3I, characterized in a single crystal XRD study and theoretically investigated at the DFT level of theory.
摘要
C70(CF3)16和C70(CF3)18是首批包含一对相邻CF3基团的三氟甲基化富勒烯衍生物，它们是从C70与CF3I反应所得的混合物中分离出来的，通过单晶X射线衍射研究对其进行了表征，并在密度泛函理论（DFT）水平上进行了理论研究。
相似文献
1
Preparation, crystallographic characterization and theoretical study of C70(CF3)16 and C70(CF3)18.
Chem Commun (Camb). 2006 Jun 21(23):2463-5. doi: 10.1039/b603201j. Epub 2006 May 3.
2
Preparation, crystallographic characterization and theoretical study of two isomers of C70(CF3)12.
Chem Commun (Camb). 2006 Apr 28(16):1778-80. doi: 10.1039/b518422c. Epub 2006 Mar 17.
3
Synthesis, characterization, and theoretical study of stable isomers of C70(CF3)n (n = 2, 4, 6, 8, 10).
Chemistry. 2006 May 3;12(14):3876-89. doi: 10.1002/chem.200501346.
4
New trifluoromethylated derivatives of [60]fullerene, C60(CF3)n with n = 12 and 14.
Chem Commun (Camb). 2007 Dec 7(45):4794-6. doi: 10.1039/b709684d. Epub 2007 Sep 5.
5
Synthesis, spectroscopic and electrochemical characterization, and DFT study of seventeen C70(CF3)n derivatives (n=2, 4, 6, 8, 10, 12).
Chemistry. 2008;14(1):107-21. doi: 10.1002/chem.200700970.
6
Synthesis, structure, and 19F NMR spectra of 1,3,7,10,14,17,23,28,31,40-C60(CF3)10.
J Am Chem Soc. 2005 Jun 15;127(23):8362-75. doi: 10.1021/ja050305j.
7
Electrochemically Induced Dimerization of -C(CF) Trifluoromethylated Fullerene.
J Phys Chem A. 2021 Sep 16;125(36):7876-7883. doi: 10.1021/acs.jpca.1c05656. Epub 2021 Sep 7.
8
Transalkylation of higher trifluoromethylated fullerenes with C70: a pathway to new addition patterns of C70(CF3)8.
Chemistry. 2014 Jan 20;20(4):1126-33. doi: 10.1002/chem.201302480. Epub 2013 Dec 11.
9
Reductive Hydrogenation of Cs -C70 (CF3 )8 and C1 -C70 (CF3 )10.
Chem Asian J. 2016 Jul 5;11(13):1945-54. doi: 10.1002/asia.201600491. Epub 2016 Jun 6.
10
Variable-temperature 19F NMR and theoretical study of 1,9- and 1,7-C60F(CF3) and C(s-) and C1-C60F17(CF3): hindered CF3 rotation and through-space J(FF) coupling.
J Am Chem Soc. 2005 Aug 17;127(32):11497-504. doi: 10.1021/ja051954y.
引用本文的文献
1
Perfluoroalkylfullerenes.
Chem Rev. 2015 Jan 28;115(2):1051-105. doi: 10.1021/cr5002595. Epub 2015 Jan 15.
Zotero 插件