利用氯化钯介导的费里尔-II重排反应合成环壳醇
Synthesis of cyclophellitol utilizing a palladium chloride mediated-Ferrier-II rearrangement.
作者信息
Takahashi Hideyo, Ikegami Shiro
机构信息
Faculty of Pharmaceutical Sciences, Teikyo University, Sagamiko, Kanagawa 199-0195, Japan.
出版信息
Molecules. 2005 Aug 31;10(8):901-11. doi: 10.3390/10080901.
Abstract
Cyclophellitol and its C3-epimer have been synthesized from5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeletonwas constructed through a Ferrier-II reaction meditated by PdCl2.
摘要
环戊糖醇及其C3-差向异构体已分别由5-烯葡萄糖苷和5-烯甘露糖苷合成。通过PdCl2介导的费里尔-II反应构建了碳环骨架。
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