Servi S, Topaloglu C
Department of Chemistry, Firat University, Faculty of Science and Arts, 23169, Elazig, Turkey.
Molecules. 2004 Jan 31;9(1):22-8. doi: 10.3390/90100022.
Heteroaryl substituted allyl and homoallyl alcohols were synthesised with two different method. Synthesis of bis-allyl ethers and homoallyl ethers were carried out via reaction of allyl bromide with allyl alcohols and homoallyl alcohols, respectively. [2.3]-Wittig Rearrangement reactions of heteroaryl substituted bis-allyl ethers were investigated using GC/MS techniques. In these reactions two unexpected products were isolated in high yield.
通过两种不同的方法合成了杂芳基取代的烯丙醇和高烯丙醇。分别通过烯丙基溴与烯丙醇和高烯丙醇反应来进行双烯丙基醚和高烯丙基醚的合成。使用气相色谱/质谱技术研究了杂芳基取代的双烯丙基醚的[2,3]-维蒂希重排反应。在这些反应中，以高产率分离出了两种意外产物。
