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限制阳离子硝酰基氮氧自由基的多金属氧酸盐盐中的磁相互作用途径。

Restricting magnetic interaction pathways in polyoxometalate salts of cationic nitronyl nitroxide free radicals.

作者信息

Tarazón Ana, Giménez-Saiz Carlos, Gómez-García Carlos J, Romero Francisco M

机构信息

Institut de Ciència Molecular, Universitat de València, Dr. Moliner 50, 46100-Burjassot, Spain.

出版信息

Molecules. 2004 Aug 31;9(9):782-91. doi: 10.3390/90900782.

DOI:10.3390/90900782
PMID:18007477
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6147456/
Abstract

Salts 1 and 2 that combine the [W6O19]2- Lindqvist anion with the cationic nitronyl nitroxide (NN) free radicals p-MepyNN+ and (n)Bu3NCH2NN+, respectively, have been synthesized and their structural and magnetic properties have been studied.

摘要

分别将[W6O19]2-林德qvist阴离子与阳离子硝酰基氮氧自由基p-MepyNN+和(n)Bu3NCH2NN+相结合的盐1和盐2已被合成，并对它们的结构和磁性进行了研究。

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本文引用的文献

1
A molecular-based magnet with a fully interlocked three-dimensional structure.一种具有完全互锁三维结构的分子基磁体。
Science. 1993 Jul 23;261(5120):447-9. doi: 10.1126/science.261.5120.447.
2
Magneto-structural characterization of metallocene-bridged nitronyl nitroxide diradicals by X-Ray, magnetic measurements, solid-state NMR spectroscopy, and ab initio calculations.通过X射线、磁性测量、固态核磁共振光谱和从头算计算对茂金属桥连硝酰基氮氧双自由基进行磁结构表征。
Chemistry. 2004 Mar 19;10(6):1355-65. doi: 10.1002/chem.200305349.
3
Syntheses of pyridine and bipyridine frameworks combining dual fluorescent and magnetic probes.结合双荧光和磁性探针的吡啶和联吡啶骨架的合成。
Org Lett. 2003 Jul 10;5(14):2397-400. doi: 10.1021/ol034474p.
4
Nitroxide Radicals as Templating Agents in the Synthesis of Magnets Based on Three-Dimensional Oxalato-Bridged Heterodimetallic Networks This work was supported by the European Union (TMR ERB 4061 PL97-0197) and the Ministerio de Ciencia y Tecnología (MCT) (Project no. MAT98-0880). C.G. and F.M.R. wish to thank the MCT for a research contract (Contrato de Reincorporación).
Angew Chem Int Ed Engl. 2001 Feb 16;40(4):792-795.