Liu Xiang, Bai Yu, Cao Jin, Wei Fu-Xiang, Zhang Xiao-Bo, Zhu Wen-Qing, Jiang Xue-Yin, Zhang Zhi-Lin
College of Material Science and Engineering, Shanghai University, Shanghai 200072, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2007 Sep;27(9):1696-9.
The blue top-emitting organic light-emitting devices with cavity effect have been fabricated. The authors used the TBADN : 3% DSAPh as emitting material of blue microcavity OLEDs. The devices consisted of Ag/ITO/CuPc/NPB/TBADN : 3% DSAPh/Alq3/LiF/Al(Ag) structure. On a patterned glass substrate, silver was deposited as reflective anode, and copper phthalocyanine (CuPc) layer as HIL and 4'-bis[N-(1-Naphthyl)-N-phenyl-amino] biphenyl (NPB) layer as HTL were made. Aluminum and silver thin films were made as semi-transparent cathode. The transmittance of aluminum and silver (Al/Ag) cathode was about 30%. In EL spectrum, the full width at half maximum (FWHM) was only 17 nm. By changing the thicknesses of ITO, highly saturated color with Commission Internationale de L'Eclairage chromaticity coordinates (CIEx,y) of (0.141, 0.049) was obtained. In the present article, the emission intensity of spectrum was studied. An appropriate cathode transmittance will result in maximal emission intensity. By using the formula of microcavity, the approximative curve that describes the change of emission intensity with cathode transmittance (or reflectance) was figured out.
已经制备了具有腔效应的蓝色顶部发光有机发光器件。作者使用TBADN:3%DSAPh作为蓝色微腔有机发光二极管的发光材料。器件由Ag/ITO/CuPc/NPB/TBADN:3%DSAPh/Alq3/LiF/Al(Ag)结构组成。在图案化玻璃基板上,沉积银作为反射阳极,并制作铜酞菁(CuPc)层作为空穴注入层(HIL)以及4'-双[N-(1-萘基)-N-苯基氨基]联苯(NPB)层作为空穴传输层(HTL)。制作铝和银薄膜作为半透明阴极。铝和银(Al/Ag)阴极的透过率约为30%。在电致发光光谱中,半高宽(FWHM)仅为17nm。通过改变ITO的厚度,获得了国际照明委员会色度坐标(CIEx,y)为(0.141,0.049)的高饱和颜色。在本文中,研究了光谱的发射强度。合适的阴极透过率将导致最大发射强度。通过使用微腔公式,得出了描述发射强度随阴极透过率(或反射率)变化的近似曲线。