Kozul Darija, Herceg Romanić Snjezana
Institut za medicinska istraZivanja i medicinu rada, Zagreb.
Arh Hig Rada Toksikol. 2007 Dec;58(4):461-9. doi: 10.2478/v10004-007-0039-x.
This paper presents a review of methods for the analysis of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in pine needles. These compounds are lipophilic, they accumulate in the biotic and abiotic part of the environment in which they are persistent, and their use is forbidden or restricted due to harmful effects on human and animal health. Pine needles are convenient for monitoring the levels of organochlorine compounds in the air because they accumulate them in wax with which they are covered. However, the presence of many other compounds makes them complex for analysis. Analytical methods for determining organochlorine compounds in pine needles include sample collection, extraction of compounds with a suitable solvent, extract clean-up from unwanted compounds and qualitative and quantitative analysis. PCBs and OCPs are present in pine needles in traces, and every part of the analytical procedure has to be as efficient and selective as possible.
本文综述了松针中多氯联苯(PCBs)和有机氯农药(OCPs)的分析方法。这些化合物具有亲脂性,它们在其持久存在的环境的生物和非生物部分中积累,并且由于对人类和动物健康的有害影响,其使用被禁止或受到限制。松针便于监测空气中有机氯化合物的含量,因为它们会将这些化合物积累在其表面覆盖的蜡中。然而,许多其他化合物的存在使得对它们的分析变得复杂。测定松针中有机氯化合物的分析方法包括样品采集、用合适的溶剂萃取化合物、从不需要的化合物中净化提取物以及定性和定量分析。多氯联苯和有机氯农药在松针中含量甚微,分析过程的每个环节都必须尽可能高效且具有选择性。