Symons M C
Philos Trans R Soc Lond B Biol Sci. 1975 Nov 6;272(915):13-28. doi: 10.1098/rstb.1975.0067.
Possible structures adopted by bulk water are discussed with special reference to the possible presence of monomeric water and the detection of 'free' -OH groups. The way in which water tends to accommodate small hydrophobic molecules is considered, with particular reference to the clathrate theory and the phenomenon of 'structure making'. Cage-pairing and cage-sharing processes are described. Consideration of the way water solvates cations and anions is followed by a discussion of the way these solvated ions interact with the bulk medium. Large symmetrical alkylammonium ions probably encourage clathrate cage formation, at least at low temperatures. Particular reference is made to the use of infrared, Raman, ultraviolet, n.m.r. and e.s.r. spectroscopic techniques to the study of water and aqueous solutions.
本文讨论了大量水可能采取的结构，特别提及了单体水的可能存在以及“游离”-OH基团的检测。文中考虑了水容纳小疏水分子的方式，尤其参考了笼形包合物理论和“结构形成”现象。描述了笼对和笼共享过程。在考虑水溶剂化阳离子和阴离子的方式之后，讨论了这些溶剂化离子与大量介质相互作用的方式。至少在低温下，大的对称烷基铵离子可能会促进笼形包合物笼的形成。特别提到了使用红外、拉曼、紫外、核磁共振和电子自旋共振光谱技术来研究水和水溶液。
