首例混合钼-钨封端-凯琴多金属氧酸盐配合物{[Co(dien)]4[(AsVO4)MoV8WVI4O33(μ2-OH)3]}.2H2O的水热合成及结构表征
Hydrothermal synthesis and structural characterization of the first mixed molybdenum-tungsten capped-keggin polyoxometal complex: {[Co(dien)]4[(AsVO4)MoV8WVI4O33(micro2-OH)3]}.2H2O.
作者信息
Yu Hai-Hui, Cui Xiao-Bing, Cui Ji-Wen, Kong Li, Duan Wei-Jie, Xu Ji-Qing, Wang Tie-Gang
机构信息
College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130023, PR China.
出版信息
Dalton Trans. 2008 Jan 14(2):195-7. doi: 10.1039/b711604g. Epub 2007 Oct 19.
DOI:10.1039/b711604g
PMID:18097484
Abstract
The first polyoxometal complex possessing affirmatory mixed molybdenum-tungsten capped Keggin-type structure has been hydrothermally synthesized.
摘要
首个具有确定的钼钨混合封端的Keggin型结构的多金属氧酸盐配合物已通过水热法合成。
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