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第三个千年伊始的有序介孔材料:制备杂化及非硅质变体的新策略。

Ordered mesoporous materials at the beginning of the third millennium: new strategies to create hybrid and non-siliceous variants.

作者信息

Van Der Voort Pascal, Vercaemst Carl, Schaubroeck David, Verpoort Francis

机构信息

University of Ghent, Department of Inorganic and Physical Chemistry, Centre for Ordered Materials, Organometallics and Catalysis (COMOC), Krijgslaan 281, B-9000, Ghent, Belgium.

出版信息

Phys Chem Chem Phys. 2008 Jan 21;10(3):347-60. doi: 10.1039/b707388g. Epub 2007 Aug 9.

Abstract

In recent years, research efforts in the field of ordered mesoporous materials are shifting towards either hybrid materials, containing both inorganic (typically silica) and organic functionalities, or towards variants that do not contain silica at all. Promising examples of hybrid materials are periodic mesoporous organosilicas (PMOs); examples of non-siliceous mesoporous materials are carbons, polymers and metal oxides. They can be further tuned to obtain structures with a wide range of functional groups, and are candidates for applications in adsorption, catalysis, sensoring, microelectronics and several other applications.

摘要

近年来,有序介孔材料领域的研究工作正朝着两种方向发展,一是制备包含无机(通常为二氧化硅)和有机官能团的杂化材料,二是制备完全不含二氧化硅的变体材料。杂化材料的典型代表是周期性介孔有机硅(PMO);非硅质介孔材料的例子有碳、聚合物和金属氧化物。它们可以进一步调整以获得具有广泛官能团的结构,并且是吸附、催化、传感、微电子及其他多种应用的候选材料。

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