Soleimani Mansooreh, Kaghazchi Tahereh
Department of Chemical Engineering, AmirKabir University of Technology, No. 424, Hafez Avenue, P.O. Box 15875, 4413 Tehran, Iran.
Bioresour Technol. 2008 Sep;99(13):5374-83. doi: 10.1016/j.biortech.2007.11.021. Epub 2008 Feb 21.
In this study, hard shell of apricot stones was selected from agricultural solid wastes to prepare effective and low cost adsorbent for the gold separation from gold-plating wastewater. Different adsorption parameters like adsorbent dose, particle size of activated carbon, pH and agitation speed of mixing on the gold adsorption were studied. The results showed that under the optimum operating conditions, more than 98% of gold was adsorbed onto activated carbon after only 3h. The equilibrium adsorption data were well described by the Freundlich and Langmuir isotherms. Isotherms have been used to obtain thermodynamic parameters. Gold desorption studies were performed with aqueous solution mixture of sodium hydroxide and organic solvents at ambient temperatures. Quantitative recovery of gold ions is possible by this method. As hard shell of apricot stones is a discarded as waste from agricultural and food industries, the prepared activated carbon is expected to be an economical product for gold ion recovery from wastewater.
在本研究中,从农业固体废物中选取杏核硬壳,制备用于从镀金废水中分离金的高效低成本吸附剂。研究了吸附剂用量、活性炭粒径、pH值以及混合搅拌速度等不同吸附参数对金吸附的影响。结果表明,在最佳操作条件下,仅3小时后超过98%的金就被吸附到活性炭上。Freundlich和Langmuir等温线能很好地描述平衡吸附数据。等温线已用于获取热力学参数。在环境温度下,用氢氧化钠水溶液和有机溶剂的混合溶液进行金的解吸研究。通过该方法可以定量回收金离子。由于杏核硬壳是农业和食品工业废弃的废料,预计制备的活性炭将是一种从废水中回收金离子的经济产品。