Krishnakumar V, Sivakumar S, Nagalakshmi R
Department of Physics, Periyar University, Salem 636011, India.
Spectrochim Acta A Mol Biomol Spectrosc. 2008 Nov 1;71(1):119-24. doi: 10.1016/j.saa.2007.11.017. Epub 2007 Nov 29.
Bisglycinehydrogenchloride (BGHC) an intriguing material for frequency conversion has been grown by slow evaporation solution growth technique at room temperature. Their structural, optical and physicochemical properties were characterized by X-ray powder diffraction, FTIR, Raman and UV-vis spectra. The title crystal has found to crystallize into noncentrosymmetric orthorhombic P2(1)2(1)2(1) space group. The material has a wide transparency in the entire visible region. It is found that the cutoff wavelength lies in the UV region. The mechanical response of the crystal has been studied using Vickers microhardness technique. The Kurtz powder second harmonic generation test shows that the compound is a prospective crystalline material for second order nonlinear optical application.
双甘氨酸盐酸盐(BGHC)是一种用于频率转换的有趣材料,已通过室温下的缓慢蒸发溶液生长技术生长出来。通过X射线粉末衍射、傅里叶变换红外光谱(FTIR)、拉曼光谱和紫外可见光谱对其结构、光学和物理化学性质进行了表征。发现该标题晶体结晶为非中心对称的正交晶系P2(1)2(1)2(1)空间群。该材料在整个可见光区域具有宽透明度。发现截止波长位于紫外区域。使用维氏显微硬度技术研究了晶体的力学响应。库尔茨粉末二次谐波产生测试表明,该化合物是用于二阶非线性光学应用的有前景的晶体材料。