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一种新型非线性光学单晶:L-盐酸鸟氨酸的晶体生长、结构、光学、力学和热学性质

Crystal growth, structural, optical, mechanical and thermal properties of a new nonlinear optical single crystal: L-Ornithine monohydrochloride.

作者信息

Balakrishnan T, Ramamurthi K

机构信息

Crystal Growth and Thin Film Laboratory, School of Physics, Bharathidasan University, Tiruchirappalli 620024, Tamil Nadu, India.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2009 Mar;72(2):269-73. doi: 10.1016/j.saa.2008.09.030. Epub 2008 Oct 19.

Abstract

Amino acid family crystals exhibit excellent nonlinear optical and electro optical properties. l-Ornithine monohydrochloride single crystal, belongs to the amino acid group, was grown by the slow evaporation solution growth technique at room temperature. The grown crystals were characterized by single crystal and powder X-ray diffraction analysis, Fourier transform infrared (FTIR) spectroscopy, TGA, DTA and DSC analyses. UV-vis-NIR spectrum shows excellent transmission in the UV, visible and NIR region (300-1600nm). The mechanical properties of grown crystals were studied using Vickers microhardness tester. Its second harmonic generation efficiency was tested using Nd:YAG laser and is 1.25 times that of KDP.

摘要

氨基酸族晶体具有优异的非线性光学和电光性能。L-盐酸鸟氨酸单晶属于氨基酸类,通过室温下缓慢蒸发溶液生长技术生长而成。通过单晶和粉末X射线衍射分析、傅里叶变换红外(FTIR)光谱、热重分析(TGA)、差热分析(DTA)和差示扫描量热法(DSC)分析对生长的晶体进行了表征。紫外-可见-近红外光谱显示在紫外、可见和近红外区域(300-1600nm)具有优异的透过率。使用维氏显微硬度测试仪研究了生长晶体的力学性能。使用Nd:YAG激光测试了其二次谐波产生效率,是磷酸二氢钾(KDP)的1.25倍。

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