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阴离子胶束在基于猝灭的金属离子荧光传感中的显著增强应用。

Application of anionic micelle for dramatic enhancement in the quenching-based metal ion fluorosensing.

作者信息

Das Paramita, Mallick Arabinda, Sarkar Deboleena, Chattopadhyay Nitin

机构信息

Department of Chemistry, Jadavpur University, Calcutta 700 032, India.

出版信息

J Colloid Interface Sci. 2008 Apr 1;320(1):9-14. doi: 10.1016/j.jcis.2007.12.026. Epub 2007 Dec 23.

Abstract

We introduce a simple and efficient strategy to enhance the efficiency of a quenching-based fluorosensor for metal ions by several orders of magnitude by using commercially available anionic surfactants varying hydrophobic chain length. Anionic surfactants with a proper choice of hydrophobic chain length at their optimum concentrations are efficient to boost up the efficiency of copper ion sensor dramatically. This simple and convenient strategy is, in general, applicable to quenching-based fluorosensors, new or established, in aqueous solution. It is powerful enough to transform a virtually non-sensor fluorophore to a sensor with a commendable efficiency with the help of proper surfactant. Thus, in this communication, light has been thrown on the application of surfactants toward increasing fluorosensing efficiency of a quenching based sensor.

摘要

我们介绍了一种简单有效的策略,通过使用具有不同疏水链长度的市售阴离子表面活性剂,将基于猝灭的金属离子荧光传感器的效率提高几个数量级。在最佳浓度下选择具有合适疏水链长度的阴离子表面活性剂,能显著提高铜离子传感器的效率。一般来说,这种简单便捷的策略适用于水溶液中新型或已有的基于猝灭的荧光传感器。借助合适的表面活性剂,它强大到足以将几乎无传感功能的荧光团转变为具有良好效率的传感器。因此,在本通讯中,阐述了表面活性剂在提高基于猝灭的传感器荧光传感效率方面的应用。

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