Ajayaghosh Ayyappanpillai, Praveen Vakayil K, Vijayakumar Chakkooth
Photosciences and Photonics Group, Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science and Technology, (NIST), CSIR, Trivandrum 695 019, India.
Chem Soc Rev. 2008 Jan;37(1):109-22. doi: 10.1039/b704456a. Epub 2007 Sep 10.
The elegance and efficiency by which Nature harvests solar energy has been a source of inspiration for chemists to mimic such process with synthetic molecular and supramolecular systems. The insights gained over the years from these studies have contributed immensely to the development of advanced materials useful for organic based electronic and photonic devices. Energy transfer, being a key process in many of these devices, has been extensively studied in recent years. A major requirement for efficient energy transfer process is the proper arrangement of donors and acceptors in a few nanometers in length scale. A practical approach to this is the controlled self-assembly and gelation of chromophore based molecular systems. The present tutorial review describes the recent developments in the design of chromophore based organogels and their use as supramolecular scaffolds for excitation energy transfer studies.
大自然捕获太阳能的优雅与高效一直激励着化学家们用合成分子和超分子体系来模拟这一过程。多年来从这些研究中获得的见解极大地推动了适用于有机电子和光子器件的先进材料的发展。能量转移是许多此类器件中的关键过程,近年来已得到广泛研究。高效能量转移过程的一个主要要求是供体和受体在几纳米的长度尺度上进行适当排列。实现这一点的一种实用方法是基于发色团的分子体系的可控自组装和凝胶化。本教程综述描述了基于发色团的有机凝胶设计的最新进展及其作为用于激发能量转移研究的超分子支架的应用。