水热条件下缺位多金属氧酸盐与高核过渡金属簇的组合：首例由含新型（Cu8）簇的三明治型多金属氧酸盐构筑单元构建的（3,6）连接框架。
Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: first (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel (Cu8) cluster.
作者信息
Zhao Jun-Wei, Zhang Jie, Zheng Shou-Tian, Yang Guo-Yu
机构信息
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter and Graduate School of the Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China.
出版信息
Chem Commun (Camb). 2008 Feb 7(5):570-2. doi: 10.1039/b713510f. Epub 2007 Nov 21.
An unprecedented (3,6)-connected 3-D framework constructed from sandwich-type polyoxometalate building blocks containing a (Cu8) cluster, [Cu(H(2)O)(2)]H(2)[Cu(8)(dap)(4)(H(2)O)(2)(alpha-B-GeW(9)O(34))(2)] (dap = 1,2-diaminopropane) has been hydrothermally made, which provides a novel topological structure in transition metal substituted polyoxometalates.
一种由含（Cu8）簇的三明治型多金属氧酸盐结构单元构建而成的前所未有的（3,6）连接三维框架，[Cu(H₂O)₂]H₂[Cu₈(dap)₄(H₂O)₂(α - B - GeW₉O₃₄)₂]（dap = 1,2 - 二氨基丙烷）已通过水热法合成，它在过渡金属取代的多金属氧酸盐中提供了一种新颖的拓扑结构。
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