Shibata Takanori, Fujiwara Daisuke, Endo Kohei
Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Okubo, Shinjuku, Tokyo 169-8555, Japan.
Org Biomol Chem. 2008 Feb 7;6(3):464-7. doi: 10.1039/b717914f. Epub 2007 Dec 11.
A Rh-BINAP complex catalyzed an intermolecular and enantioselective [4 + 2] cycloaddition of 1-monosubstituted, 1,1- or 1,2-disubstituted buta-1,3-dienes with dimethyl acetylenedicarboxylate to give chiral cyclohexa-1,4-dienes.
一种铑-联萘酚膦配合物催化1-单取代、1,1-或1,2-二取代的1,3-丁二烯与乙酰基二羧酸二甲酯进行分子间对映选择性[4 + 2]环加成反应，生成手性环己-1,4-二烯。
Zotero 插件