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铜金属对Sc3N@C80金属富勒烯产率的影响。

Effect of copper metal on the yield of Sc3N@C80 metallofullerenes.

作者信息

Stevenson Steven, Mackey Mary A, Thompson M Corey, Coumbe H Louie, Madasu Praveen K, Coumbe Curtis E, Phillips J Paige

机构信息

Department of Chemistry and Biochemistry, University of Southern Mississippi, 118 College Drive, #5043, Hattiesburg, MS 39402, USA.

出版信息

Chem Commun (Camb). 2007 Nov 7(41):4263-5. doi: 10.1039/b706859j.

Abstract

The yield of Sc3N@C80 metallofullerene and fullerene extract is dramatically increased via filling cored graphite rods with copper and Sc2O3 only; when compared to 100% Sc2O3 packed rods, improvements of factors of approximately 3 and approximately 5 have been achieved for Sc3N@C80 and fullerene extract produced, respectively, with the weight percent of Cu added to the rod affecting the type and amount of fullerene produced.

摘要

仅通过用铜和氧化钪填充有芯石墨棒,Sc3N@C80金属富勒烯和富勒烯提取物的产量就会显著提高;与填充100%氧化钪的棒相比,所生产的Sc3N@C80和富勒烯提取物分别实现了约3倍和约5倍的产量提升,添加到棒中的铜的重量百分比会影响所生产富勒烯的类型和数量。

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