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考古学中的微衰减全反射光谱成像:在玛雅壁画和石膏墙面装饰中的应用

Micro-attenuated total reflection spectral imaging in archaeology: application to Maya paint and plaster wall decorations.

作者信息

Goodall Rosemary A, Hall Jay, Sharer Robert J, Traxler Loa, Rintoul Llew, Fredericks Peter M

机构信息

School of Physical and Chemical Sciences, Queensland University of Technology, GPO Box 2434, Brisbane, Qld 4001, Australia.

出版信息

Appl Spectrosc. 2008 Jan;62(1):10-6. doi: 10.1366/000370208783412627.

DOI:10.1366/000370208783412627
PMID:18230201
Abstract

Fourier transform infrared (FT-IR) attenuated total reflection (ATR) imaging has been successfully used to identify individual mineral components of ancient Maya paint. The high spatial resolution of a micro FT-IR-ATR system in combination with a focal plane array detector has allowed individual particles in the paint to be resolved and identified from their spectra. This system has been used in combination with micro-Raman spectroscopy to characterize the paint, which was found to be a mixture of hematite and silicate particles with minor amounts of calcite, carbon, and magnetite particles in a sub-micrometer hematite and calcite matrix. The underlying stucco was also investigated and found to be a combination of calcite with fine carbon particles, making a dark sub-ground for the paint.

摘要

傅里叶变换红外(FT-IR)衰减全反射(ATR)成像已成功用于识别古代玛雅颜料中的各个矿物成分。微型傅里叶变换红外衰减全反射(FT-IR-ATR)系统的高空间分辨率与焦平面阵列探测器相结合,使得能够从颜料中的光谱分辨并识别单个颗粒。该系统已与显微拉曼光谱联用,用于表征这种颜料,结果发现它是赤铁矿和硅酸盐颗粒的混合物,在亚微米级的赤铁矿和方解石基质中含有少量方解石、碳和磁铁矿颗粒。还对底层灰泥进行了研究,发现它是方解石与细碳颗粒的组合,形成了颜料的深色底层。

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