Shimizu Y, Akimoto H, Tsujii H, Tajima A, Kato R
RIKEN, Wako, Saitama 351-0198, Japan.
Phys Rev Lett. 2007 Dec 21;99(25):256403. doi: 10.1103/PhysRevLett.99.256403. Epub 2007 Dec 19.
We have investigated the Mott transition in a quasi-two-dimensional Mott insulator EtMe{3}P[Pd(dmit){2}]{2} with a spin-frustrated triangular-lattice in hydrostatic pressure and magnetic-field [Et and Me denote C2H5 and CH3, respectively, and Pd(dmit){2} (dmit=1,3-dithiole-2-thione-4,5-dithiolate,dithiolate) is an electron-acceptor molecule]. In the pressure-temperature (P-T) phase diagram, a valence-bond solid phase is found to neighbor the superconductor and metal phases at low temperatures. The profile of the phase diagram is common to those of Mott insulators with antiferromagnetic order. In contrast to the antiferromagnetic Mott insulators, the resistivity in the metallic phase exhibits anomalous temperature dependence, rho=rho{0}+AT(2.5).
我们研究了具有自旋阻挫三角晶格的准二维莫特绝缘体EtMe₃P[Pd(dmit)₂]₂在静水压力和磁场中的莫特转变[Et和Me分别表示C₂H₅和CH₃,Pd(dmit)₂(dmit = 1,3 - 二硫杂环戊烯 - 2 - 硫酮 - 4,5 - 二硫醇盐)是一种电子受体分子]。在压力 - 温度(P - T)相图中,发现价键固相在低温下与超导体和金属相相邻。该相图的轮廓与具有反铁磁序的莫特绝缘体的相图相同。与反铁磁莫特绝缘体不同,金属相中的电阻率表现出异常的温度依赖性,ρ = ρ₀ + AT².⁵ 。