A gas-phase study of the preferential solvation of Mn(2+) in mixed water/methanol clusters.
作者信息
Duncombe Bridgette J, Rydén Jens O S, Puskar Ljilijana, Cox Hazel, Stace Anthony J
机构信息
Department of Physical Chemistry, School of Chemistry, University of Nottingham, University Park, Nottingham, UK.
出版信息
J Am Soc Mass Spectrom. 2008 Apr;19(4):520-30. doi: 10.1016/j.jasms.2007.12.004. Epub 2007 Dec 27.
PMID:18258449
Abstract
The kinetic shift that exists between two competing unimolecular fragmentation processes has been used to establish whether or not gas-phase Mn(2+) exhibits preferential solvation when forming mixed clusters with water and methanol. Supported by molecular orbital calculations, these first results for a metal dication demonstrate that Mn(2+) prefers to be solvated by methanol in the primary solvation shell.
摘要
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