Oliveri Christopher G, Nguyen Sonbinh T, Mirkin Chad A
Department of Chemistry and International Institute for Nanotechnology, Northwestern University, Evanston, Illinois 60208-3113, USA.
Inorg Chem. 2008 Apr 7;47(7):2755-63. doi: 10.1021/ic702150y. Epub 2008 Feb 13.
The synthesis of new hemilabile phosphine ligands and their reaction with [Rh(COE)2Cl]2 to form dissymmetric heteroligated tweezer complexes using a halide-induced ligand rearrangement reaction are reported. These complexes can undergo reactions with small-molecule ligands and elemental anions quantitatively in situ, which serve to regulate the porphyrin-porphyrin distances and interactions within the assembly.
报道了新型半不稳定膦配体的合成及其与二氯（环辛烯）铑（II）通过卤化物诱导的配体重排反应形成不对称杂配钳形配合物的过程。这些配合物可与小分子配体和元素阴离子在原位定量发生反应，用于调节组装体中卟啉 - 卟啉的距离和相互作用。
