一种用于合成刺激响应性异配位共面卟啉镊子配合物的高度模块化和收敛性方法。
A highly modular and convergent approach for the synthesis of stimulant-responsive heteroligated cofacial porphyrin tweezer complexes.
作者信息
Oliveri Christopher G, Nguyen Sonbinh T, Mirkin Chad A
机构信息
Department of Chemistry and International Institute for Nanotechnology, Northwestern University, Evanston, Illinois 60208-3113, USA.
出版信息
Inorg Chem. 2008 Apr 7;47(7):2755-63. doi: 10.1021/ic702150y. Epub 2008 Feb 13.
The synthesis of new hemilabile phosphine ligands and their reaction with [Rh(COE)2Cl]2 to form dissymmetric heteroligated tweezer complexes using a halide-induced ligand rearrangement reaction are reported. These complexes can undergo reactions with small-molecule ligands and elemental anions quantitatively in situ, which serve to regulate the porphyrin-porphyrin distances and interactions within the assembly.
报道了新型半不稳定膦配体的合成及其与二氯（环辛烯）铑（II）通过卤化物诱导的配体重排反应形成不对称杂配钳形配合物的过程。这些配合物可与小分子配体和元素阴离子在原位定量发生反应，用于调节组装体中卟啉 - 卟啉的距离和相互作用。
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