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Two enantiomers of [Cu(3)(mnt)(3)](3-) as ligands to Cu(i) or Ag(i) in building [Cu(6)M(2)(mnt)(6)](4-) complexes (M = Cu or Ag) with the reversal of the reaction by X(-) (X = Cl, Br).

作者信息

Maiti Biplab K, Pal Kuntal, Sarkar Sabyasachi

机构信息

Department of Chemistry, Indian Institute of Technology, Kanpur, 208016, India.

出版信息

Dalton Trans. 2008 Feb 28(8):1003-8. doi: 10.1039/b714550k. Epub 2007 Dec 18.

DOI:10.1039/b714550k
PMID:18274680
Abstract

Two enantiomers of Bu(4)N[Cu(3)(mnt)(3)] () formed by Na(2)(mnt) (mnt = maleonitriledithiolate, S(2)C(2)(CN)(2)) and CuCl in a 1 : 1 molar ratio react further with MCl (M = Cu or Ag) involving both the enantiomers of to produce the larger complex, Bu(4)N[Cu(6)M(2)(mnt)(6)] (M = Cu (2), Ag (3)) from which the capped Cu(+) or Ag(+) ion can readily be removed by Bu(4)NX (X = Cl, Br), reverting or back to . Such reversal does not work with non-coordinating anions like BF(4)(-), ClO(4)(-) and PF(6)(-).

摘要

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