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镧浓度对0.57BiFeO3 - 0.43PbTiO3晶体固溶体结构和介电性能的影响

Effects of La concentration on the structural and dielectric properties of 0.57BiFeO3-0.43PbTiO3 crystalline solutions.

作者信息

Chen Jianguo, Cheng Jinrong, Yu Shengwen, Jin Dengren, Meng Zhongyan

机构信息

Department of Material Science and Engineering, Shanghai University, Shanghai, 200072, PR China.

出版信息

IEEE Trans Ultrason Ferroelectr Freq Control. 2007 Dec;54(12):2637-40. doi: 10.1109/TUFFC.2007.591.

Abstract

Crystalline solutions of 0.57(Bi(1-x)La(x))FeO(3)-0.43PbTiO(3) (BLF-PT) for x = 0, 0.1, 0.2, and 0.3 were fabricated by the traditional solid state reaction method. X-ray diffraction analysis revealed that the tetragonal torhombohedral phase transformation of BLF-PT occurred with an increase of the La content. The dielectric and ferroelectric properties of BLF-PT were investigated at room temperature for different La contents. BLF-PT revealed strong ferroelectric characteristics for the lower La composition, and transferred to relaxor ferroelectrics for x 0.2. The dielectric constant and remanent polarization were 1461 and 33.5 microC/cm(2), respectively, for BLF-PT of x = 0.2. The dielectric constant and polarization of BLF-PT were enhanced simultaneously with increasing La content. Our results demonstrate that BLF-PT is a competitive piezoelectric ceramic.

摘要

采用传统固相反应法制备了x = 0、0.1、0.2和0.3时的0.57(Bi(1 - x)La(x))FeO(3)-0.43PbTiO(3)(BLF-PT)晶体溶液。X射线衍射分析表明,随着La含量的增加,BLF-PT发生四方-菱面体相变。研究了不同La含量的BLF-PT在室温下的介电和铁电性能。低La组成的BLF-PT表现出强铁电特性,当x>0.2时转变为弛豫铁电体。对于x = 0.2的BLF-PT,介电常数和剩余极化分别为1461和33.5 μC/cm²。随着La含量的增加,BLF-PT的介电常数和极化同时增强。我们的结果表明,BLF-PT是一种有竞争力的压电陶瓷。

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