金（I）催化的联烯分子内氢芳基化反应。
Gold(I)-catalyzed intramolecular hydroarylation of allenes.
作者信息
Tarselli Michael A, Gagné Michel R
机构信息
Caudill Laboratories, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, USA.
出版信息
J Org Chem. 2008 Mar 21;73(6):2439-41. doi: 10.1021/jo7024948. Epub 2008 Feb 16.
Abstract
Gold(I) complexes react with 4-allenyl arenes in an exo fashion to furnish vinyl-substituted benzocycles. Phosphite gold(I) monocations were found to be optimal, and the catalyst was tolerant of ethers, esters, and pyrroles. Reactions proceeded in unpurified solvent at room temperature.
摘要
金（I）配合物以外型方式与4-烯丙基芳烃反应，生成乙烯基取代的苯并环。发现亚磷酸金（I）单阳离子是最佳的，并且该催化剂对醚、酯和吡咯具有耐受性。反应在室温下于未纯化的溶剂中进行。
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