用于酚类邻位芳基化反应的简单铑-氯膦预催化剂。
Simple rhodium-chlorophosphine pre-catalysts for the ortho-arylation of phenols.
作者信息
Bedford Robin B, Betham Michael, Caffyn Andrew J M, Charmant Jonathan P H, Lewis-Alleyne Lesley C, Long Philip D, Polo-Cerón Dorian, Prashar Sanjiv
机构信息
School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK BS8 1TS.
出版信息
Chem Commun (Camb). 2008 Feb 28(8):990-2. doi: 10.1039/b718128k. Epub 2008 Jan 10.
DOI:10.1039/b718128k
PMID:18283359
Abstract
Simple chlorodiisopropylphosphine adducts of rhodium, either pre-formed or formed in situ, prove to be highly effective catalysts for the ortho-arylation of phenols.
摘要
铑的简单氯代二异丙基膦加合物，无论是预先形成的还是原位形成的，都被证明是用于酚类邻位芳基化的高效催化剂。
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