• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Reactivity of the Ni-->B dative sigma-bond in the nickel boratrane compounds [kappa4-B(mimBut)3]NiX (X=Cl, OAc, NCS, N3): synthesis of a series of B-functionalized tris(2-mercapto-1-tert-butylimidazolyl)borato complexes, [YTmBut)]NiZ.

作者信息

Pang Keliang, Tanski Joseph M, Parkin Gerard

机构信息

Department of Chemistry, Columbia University, New York, New York 10027, USA.

出版信息

Chem Commun (Camb). 2008 Feb 28(8):1008-10. doi: 10.1039/b714466k. Epub 2008 Jan 4.

DOI:10.1039/b714466k
PMID:18283365
Abstract

The nickel boratrane complexes [kappa4-B(mimBut))3]Ni(kappa1-OAc), [kappa4-B(mimBut)3]NiNCS and [kappa4-B(mimBut)3]NiN3 are obtained via metathesis of the chloride ligand of [kappa4-B(mimBut)3]NiCl with TlOAc, KSCN and NaN3, respectively; the Ni-->B bond in these complexes is a site of reactivity, thereby providing a means of synthesizing nickel complexes that feature B-functionalized tris(mercaptoimidazolyl)borate derivatives, [YTmBut]NiZ.

摘要

相似文献

1
Reactivity of the Ni-->B dative sigma-bond in the nickel boratrane compounds [kappa4-B(mimBut)3]NiX (X=Cl, OAc, NCS, N3): synthesis of a series of B-functionalized tris(2-mercapto-1-tert-butylimidazolyl)borato complexes, [YTmBut)]NiZ.
Chem Commun (Camb). 2008 Feb 28(8):1008-10. doi: 10.1039/b714466k. Epub 2008 Jan 4.
2
Reactivity of the metal-->BX3 dative sigma-bond: 1,2-addition reactions of the Fe-->BX3 moiety of the ferraboratrane complex [kappa4-B(mimBu t)3]Fe(CO)2.
Inorg Chem. 2006 Sep 4;45(18):7056-8. doi: 10.1021/ic061353n.
3
Palladium complexes with Pd-->B dative bonds: analysis of the bonding in the palladaboratrane compound [kappa4-B(mimBut)3]Pd(PMe3).具有Pd→B配位键的钯配合物：硼杂环丁二烯钯化合物[kappa4-B(mimBut)3]Pd(PMe3)的键合分析
Chem Commun (Camb). 2006 Dec 28(48):5015-7. doi: 10.1039/b611654j. Epub 2006 Oct 12.
4
The coordination chemistry of "[BP3]NiX" platforms: targeting low-valent nickel sources as promising candidates to L3Ni=E and L3Ni(triple bond)E linkages.“[BP3]NiX”平台的配位化学：以低价镍源为目标，作为形成L3Ni=E和L3Ni（三键）E键的有前景候选物。
Inorg Chem. 2004 Jul 26;43(15):4645-62. doi: 10.1021/ic049936p.
5
A simple route to single-scorpionate nickel(II) complexes with minimum steric requirements.一种制备具有最小空间位阻要求的单螯合镍（II）配合物的简单方法。
Inorg Chem. 2009 Apr 20;48(8):3535-41. doi: 10.1021/ic8015645.
6
Molecular structures of tris(2-mercapto-1-tert-butylimidazolyl)hydroborato and tris(2-mercapto-1-adamantylimidazolyl)hydroborato sodium complexes: analysis of [Tm(R)] ligand coordination modes and conformations.三（2-巯基-1-叔丁基咪唑基）硼氢化钠和三（2-巯基-1-金刚烷基咪唑基）硼氢化钠配合物的分子结构：[Tm(R)]配体配位模式与构象分析
Dalton Trans. 2014 Jul 28;43(28):10852-65. doi: 10.1039/c4dt01271b.
7
Mononuclear nickel(III) complexes [Ni(III)(OR)(P(C6H3-3-SiMe3-2-S)3)](-) (R = Me, Ph) containing the terminal alkoxide ligand: relevance to the nickel site of oxidized-form [NiFe] hydrogenases.含有末端醇盐配体的单核镍(III)配合物[Ni(III)(OR)(P(C6H3-3-SiMe3-2-S)3)](-)（R = 甲基、苯基）：与氧化态[NiFe]氢化酶的镍位点的相关性
Inorg Chem. 2008 Sep 1;47(17):7908-13. doi: 10.1021/ic801069t. Epub 2008 Aug 2.
8
Ni(II)/H(2)O(2) reactivity in bis[(pyridin-2-yl)methyl]amine tridentate ligand system. aromatic hydroxylation reaction by bis(mu-oxo)dinickel(III) complex.双[（吡啶-2-基）甲基]胺三齿配体体系中镍（II）/过氧化氢的反应活性。双（μ-氧）二镍（III）配合物引发的芳香族羟基化反应。
Inorg Chem. 2009 Jun 1;48(11):4997-5004. doi: 10.1021/ic900059m.
9
Terminal nickel(ii) amide, alkoxide, and thiolate complexes containing amido diphosphine ligands of the type [N(o-C6H4PR2)2]- (R = Ph, (i)Pr, Cy).含有[N(o-C6H4PR2)2]-（R = Ph、(i)Pr、Cy）类型酰胺二膦配体的末端镍（II）酰胺、醇盐和硫醇盐配合物。
Dalton Trans. 2008 Jul 7(25):3320-7. doi: 10.1039/b719894a. Epub 2008 May 8.
10
Nickel complexes of a pincer amidobis(amine) ligand: synthesis, structure, and activity in stoichiometric and catalytic C-C bond-forming reactions of alkyl halides.钳形酰胺双（胺）配体的镍配合物：卤代烷烃化学计量和催化碳-碳键形成反应中的合成、结构及活性
Chemistry. 2009;15(15):3889-99. doi: 10.1002/chem.200802059.

引用本文的文献

1
Triel Bonds between BH/CHBX and M(MDA) (X = H, CN, F, CH, NH; M = Ni, Pd, Pt, MDA = Enolated Malondialdehyde) and Group 10 Transition Metal Electron Donors.BH/CHBX与M(MDA)（X = H、CN、F、CH、NH；M = Ni、Pd、Pt、MDA = 烯醇化丙二醛）之间的三中心键以及第10族过渡金属电子给体。
Molecules. 2024 Apr 3;29(7):1602. doi: 10.3390/molecules29071602.
2
Systematic evaluation of the electronic effect of aluminum-containing ligands in iridium-aluminum and rhodium-aluminum bimetallic complexes.铱-铝和铑-铝双金属配合物中含铝配体电子效应的系统评估。
Dalton Trans. 2020 Oct 7;49(37):13029-13043. doi: 10.1039/d0dt02472d. Epub 2020 Sep 11.
3
Metal-only Lewis pairs between group 10 metals and Tl(i) or Ag(i): insights into the electronic consequences of Z-type ligand binding.
第10族金属与Tl(i)或Ag(i)之间仅含金属的路易斯酸碱对：对Z型配体结合电子效应的见解
Chem Sci. 2015 Dec 1;6(12):7169-7178. doi: 10.1039/c5sc03104d. Epub 2015 Sep 17.
4
Synthesis and Structural Characterization of 1-Arylimidazole-2-thiones and ,'-Aryldiethoxyethylthioureas with Electronically Diverse Substituents: A Manifold of Hydrogen Bonding Networks.具有不同电子取代基的1-芳基咪唑-2-硫酮和,'-芳基二乙氧基乙基硫脲的合成与结构表征：多种氢键网络
New J Chem. 2014 Sep 1;38(9):4071-4082. doi: 10.1039/C4NJ00521J.
5
Terminal iron dinitrogen and iron imide complexes supported by a tris(phosphino)borane ligand.由三（膦基）硼烷配体支撑的末端二氮铁和酰亚胺铁配合物。
Angew Chem Int Ed Engl. 2011 Feb 25;50(9):2063-7. doi: 10.1002/anie.201006918. Epub 2011 Jan 26.
6
2-Mercapto-1-t-butylimidazolyl as a Bridging Ligand: Synthesis and Structural Characterization of Nickel and Palladium Paddlewheel Complexes.作为桥连配体的2-巯基-1-叔丁基咪唑基：镍和钯桨轮配合物的合成与结构表征
Inorganica Chim Acta. 2009 Sep 15;362(12):4609-4615. doi: 10.1016/j.ica.2009.05.025.