Rüdiger Stephan, Kemnitz Erhard
Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Strasse 2, D-12489, Berlin, Germany.
Dalton Trans. 2008 Mar 7(9):1117-27. doi: 10.1039/b716483a. Epub 2008 Jan 7.
The recently developed fluorolytic sol-gel route to metal fluorides opens a very broad range of both scientific and technical applications of the accessible high surface area metal fluorides, many of them have already been applied or tested. Specific chemical properties such as high Lewis acidity and physical properties such as high surface area, meso-porosity and nano-size as well as the possibility to apply metal fluorides on surfaces via a non-aqueous sol make the fluorolytic synthesis route a very versatile one. The scope of its scientific and technical use and the state of the art are presented.
最近开发的通过氟解溶胶-凝胶法制备金属氟化物的方法，为可获得的高比表面积金属氟化物开辟了非常广泛的科学和技术应用领域，其中许多已经得到应用或测试。诸如高路易斯酸度等特定化学性质以及高比表面积、中孔性和纳米尺寸等物理性质，以及通过非水溶胶将金属氟化物应用于表面的可能性，使得氟解合成路线非常通用。本文介绍了其科学和技术用途的范围以及当前的技术水平。
