Deschamps Michaël, Fayon Franck, Hiet Julien, Ferru Geoffroy, Derieppe Marc, Pellerin Nadia, Massiot Dominique
CRMHT-CNRS UPR4212 and Université d'Orléans, 1D Avenue de la Recherche Scientifique, 45071 Orléans Cedex 2, France.
Phys Chem Chem Phys. 2008 Mar 7;10(9):1298-303. doi: 10.1039/b716319c. Epub 2008 Jan 2.
Scalar couplings, recoupled or full dipolar interactions can be used to characterize multinuclear structural molecular motifs in solids, by counting the neighbouring spins in solid-state NMR, opening new ways for the differentiation of overlapping spectral responses which is a limiting factor in many high resolution experiments carried out on disordered systems.
标量耦合、重新耦合或全偶极相互作用可用于通过固态核磁共振中对相邻自旋的计数来表征固体中的多核结构分子基序,为区分重叠光谱响应开辟了新途径,而重叠光谱响应是在无序系统上进行的许多高分辨率实验中的一个限制因素。