Crystallization induced chiral locking of a central labile core in a star-shaped tetra-nuclear complex.
作者信息
Sato Hisako, Furuno Yuka, Fukuda Yutaka, Okamoto Kentaro, Yamagishi Akihiko
机构信息
The University of Tokyo, Tokyo, Japan and PRESTO, JST, Japan.
出版信息
Dalton Trans. 2008 Mar 14(10):1283-5. doi: 10.1039/b717429b. Epub 2008 Feb 1.
DOI:10.1039/b717429b
PMID:18305837
Abstract
The central labile Al(III) core of a star-shaped tetra-nuclear metal complex, [{Delta-Ru(III)(acac)(2)(taet)}(3)Al(III)] (acac = acetylacetonato; taet = tetraacetylethanato), which was synthesized by reacting Delta-[Ru(III)(acac)(2)(taetH)] (taetH = singly protonated taet) with an Al(III) ion in solution, was found to be locked as a Lambda-form in the solid state.
摘要
Zotero 插件