星爆型四核钌(III)配合物在手性修饰粘土表面的分子识别。

Molecular recognition of star-burst tetranuclear Ru(III) complexes on a chirally modified clay surface.

机构信息

Faculty of Science, Ochanomizu University, Tokyo, 112-8610, Japan.

出版信息

Chem Commun (Camb). 2010 Aug 14;46(30):5473-5. doi: 10.1039/c0cc00685h. Epub 2010 Jul 2.

PMID:20596573

Abstract

Star-burst tetranuclear Ru(iii) complexes, Delta-(or Lambda-)[{Delta-(or Lambda-)-Ru(iii)(acac)(2)(taet)}(3)Ru(iii)] (acac = acetylacetonato; taet = tetraacetylethanato), were prepared and resolved into eight enantiomers on a column packed with an ion-exchange adduct of a clay and Delta-Ru(ii)(phen)(3) (phen = 1,10-phenanthroline), demonstrating that the dual chiralities of the central and peripheral regions were discriminated on the modified clay surface.

摘要

星爆四核钌(III)配合物，Delta-(或 Lambda-)[{Delta-(或 Lambda-)-钌(III)(乙酰丙酮)(2)(taet)}(3)钌(III)]（acac = 乙酰丙酮根；taet = 四乙酰基乙醇酸根），被制备并在手性柱上分离为八种对映异构体，该手性柱填充有粘土与 Delta-钌(II)(phen)(3)（phen = 1,10-菲咯啉）的离子交换加合物，这表明中央和外围区域的双重手性在改性粘土表面上得到了区分。