环戊二烯基（二甲基异丙基膦）氢化铁硅基化合物：非经典的硅氢化二氢铁化合物
Cp(Pri2MeP)FeH2SiR3: nonclassical iron silyl dihydride.
作者信息
Gutsulyak Dmitry V, Kuzmina Lyudmila G, Howard Judith A K, Vyboishchikov Sergei F, Nikonov Georgii I
机构信息
Chemistry Department, Brock University, 500 Glenridge Avenue, St. Catharines, ON, L2S 3A1, Canada.
出版信息
J Am Chem Soc. 2008 Mar 26;130(12):3732-3. doi: 10.1021/ja800983n. Epub 2008 Mar 4.
PMID:18314992
Abstract
Reactions of a new borohydride complex 2 with hydrosilanes afford half-sandwich dihydride silyl complexes 3a-f. According to X-ray and DFT evidence complexes 3 have unprecedented double H...Si...H interligand interactions.
摘要
新型硼氢化物配合物2与硅烷反应生成半夹心二氢硅基配合物3a - f。根据X射线和密度泛函理论（DFT）证据，配合物3具有前所未有的双H…Si…H配体间相互作用。
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