Kolev Tsonko M, Koleva Bojidarka B, Spiteller Michael, Sheldrick William S, Mayer-Figge Heike
Institute of Organic Chemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str. build. 9, 1113 Sofia, Bulgaria.
Amino Acids. 2009 Feb;36(2):185-93. doi: 10.1007/s00726-008-0046-5. Epub 2008 Mar 4.
The synthesis, isolation, spectroscopic and structural elucidation of sympathomimetic amine, tyramine dihydrogenphosphate are of interest due to its biological activity and the establishing correlation between spectroscopic properties and structure. The complex approach for investigation included single crystal X-ray diffraction, new technique in linear-polarized IR-spectroscopy in solid state and quantum chemical calculations with a view to predict the electronic structure and vibrational data of interacting species in entitled compound, the correlation structure-spectroscopic properties as well as the influence of intermolecular interaction on IR-characteristic bands are carried out.
拟交感神经胺磷酸二氢酪胺的合成、分离、光谱分析及结构解析因其生物活性以及光谱性质与结构之间的关联而备受关注。研究采用的综合方法包括单晶X射线衍射、固态线性偏振红外光谱新技术以及量子化学计算，旨在预测该化合物中相互作用物种的电子结构和振动数据，开展结构-光谱性质的相关性研究以及分子间相互作用对红外特征谱带的影响研究。
