类卟啉多核铑配合物的合成与动态结构
Synthesis and dynamic structure of multinuclear Rh complexes of porphyrinoids.
作者信息
Setsune Jun-ichiro, Toda Masayuki, Yoshida Takafumi
机构信息
Department of Chemistry, Graduate School of Science, Kobe University, 1-1 Rokkodai-cho, Nada-ku, 657-8501 Kobe, Japan.
出版信息
Chem Commun (Camb). 2008 Mar 28(12):1425-7. doi: 10.1039/b717022j. Epub 2008 Feb 19.
DOI:10.1039/b717022j
PMID:18338044
Abstract
Large porphyrinoids with three Rh(CO)2 groups at their dipyrrin units shows two-step metal transposition through the macrocycle in solution and the equilibrium between the C3v-isomer and the Cs-isomer depends on the solvent polarity.
摘要
在其二吡咯单元带有三个Rh(CO)₂基团的大型卟啉类化合物在溶液中通过大环显示出两步金属转位，并且C₃ᵥ异构体和Cs异构体之间的平衡取决于溶剂极性。
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