Zhao Yu-Jun, Loh Teck-Peng
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 1 Nanyang Walk, Block 5 level 3, Singapore639798.
Chem Commun (Camb). 2008 Mar 28(12):1434-6. doi: 10.1039/b714474a. Epub 2008 Jan 24.
This communication describes a highly efficient intermolecular polyene cyclization method using steroidal acetals as the initiators to synthesize tetracyclic terpenoids; both good yields and good asymmetric induction were obtained.
本通讯描述了一种高效的分子间多烯环化方法,该方法使用甾体缩醛作为引发剂来合成四环萜类化合物;获得了良好的产率和良好的不对称诱导效果。